Naar inhoud springen

Sjabloon:Tabel Exact/Elektronenaffiniteit Meer-atomige deeltjes

Koppelingen toevoegen
Uit Wikibooks

Sjabloondocumentatie

Deze tabel is als sjabloon gemaakt om hem in meerdere boeken te kunnen gebruiken. Kijk met de knop "Links naar deze pagina" welke boeken/pagina's dat zijn.

Dit sjabloon bevat een lijst met elektronenaffiniteiten van een aantal meer-atomige deeltjes. Neem deze lijst in een pagina op door de tekst 

{{Tabel Exact/Elektronenaffiniteit Meer-atomige deeltjes}}

in de brontekst van de pagina te plaatsen. Het resultaat wordt:

De elektronenaffiniteiten, Eea, van een aantal moleculaire deeltjes zijn in onderstaande tabel weergegeven, gesorteerd op massa van de deeltjes. Door Rienstra-Kiracofe etal is een meer uitgebreide lijst samengesteld.[1]. De elektronenaffiniteit van de radicalen en zijn van alle moleculaire affiniteiten het nauwkeurigst bekend.

Molecuul Naam Massa Eea (eV) Eea (kJ/mol) Referenties
Di-atomaire deeltjes
16OH Hydroxyl 17,0068 1,827 6488(11) 176,3413(2) [2]
16OD 18,0131 1,825 53(4) 176,137(5) [3]
C2 Dikoolstof 24,0000 3,269(6) 315,4(6) [4]
CN Cyanoradicaal 26,0067 3,862(4) 372,6263 [5]
BO Boor(II)oxide 26,8100 2,508(8) 242,0(8) [6]
NO Stikstofmonoxide 30,0057 0,026(5) 2,5(5) [7]
O2 Dizuurstof 31,9980 0,450(2) 43,42(20) [8]
32SH Sulfhydryl 32,9799 2,314 7283(17) 223,3373(2) [9]
F2 Difluor 37,9968 3,08(10) 297(10) [10]
LiCl Lithiumchloride 42,3940 0,593(10) 57,2(10) [11]
Cl2 Dichloor 70,9060 2,35(8) 227(8) [10]
FeO IJzer(II)oxide 71,8440 1,4950(5) 144,25(6) [12]
Br2 Dibroom 159,8080 2,53(8) 244(8) [10]
IBr joodmonobromide 206,8085 2,512(3) 242,4(4) [13]
I2 Di-jood 253,8090 2,524(5) 243,5(5) [14]
Tri-atomaire deeltjes
NO2 Stikstofdioxide 46,0047 2,273(5) 219,3(5) [15]
O3 Ozon 47,9970 2,1028(25) 202,89(25) [16]
SO2 Zwaveldioxide 63,9701 1,107(8) 106,8(8) [17]
Grotere poly-atomaire deeltjes
CH2CHO Vinyloxy 43,0225 1,8248(+2-6) 176,07(+3-7) [18]
CH3NO2 Nitromethaan 61,0282 0,172(6) 16,6(6) [19]
HNO3 Salpeterzuur 63,0115 0,57(15) 55(14) [10]
BF3 Boortrifluoride 67,8062 2,65(10) 256(10) [20]
C6H6 Benzeen 78,0470 −0,70(14) −68(14) [21]
C6H4O2 1,4-Benzochinon 108,0293 1,860(5) 179,5(6) [22]
C2(CN)4 Tetracyano-etheen 128,0268 3,17(20) 306(20) [23]
SF6 Zwavelhexafluoride 145,9625 1,03(5) 99,4(49) [24]
POCl3 Fosforylchloride 153,3318 1,41(20) 136(20) [25]
WF6 Wolfraam(VI)fluoride 297,8304 3,5(1) 338(10) [26]
UF6 Uraniumhexafluoride 352,0204 5,06(20) 488(20) [27]
C60 Buckminsterfullereen 720,0000 2,6835(6) 258,92(6) [28]
  1. ↑ Rienstra-Kiracofe, J.C.; Tschumper, G.S.; Schaefer, H.F.; Nandi, S.; Ellison, G.B. (2002). Atomic and molecular electron affinities: Photoelectron experiments and theoretical computations 102 (1): 231–282. PMID: 11782134. DOI: 10.1021/cr990044u.
  2. ↑ Goldfarb, F.; Drag, C.; Chaibi, W.; Kröger, S.; Blondel, C.; Delsart, C. (2005). Photodetachment microscopy of the P, Q, and R branches of the OH−(v=0) to OH(v=0) detachment threshold. J. Chem. Phys. 122 (1): 014308. PMID: 15638660. DOI: 10.1063/1.1824904.
  3. ↑ Schulz, P.A.; Mead, R.D.; Jones, P.L.; Lineberger, W.C. (1982). OH− and OD− threshold photodetachment. J. Chem. Phys. 77 (3): 1153. DOI: 10.1063/1.443980.
  4. ↑ Ervin, K.M.; Lineberger, W.C. (1991). Photoelectron spectra of and . J. Phys. Chem. 95 (3): 1167. DOI: 10.1021/j100156a026.
  5. ↑ Bradforth, Stephen E.; Kim, Eun Ha; Arnold, Don W.; Neumark, Daniel M. (15 januari 1993). Photoelectron spectroscopy of CN−, NCO−, and NCS−. The Journal of Chemical Physics 98 (2): 800–810 (AIP Publishing). ISSN: 0021-9606. DOI: 10.1063/1.464244.
  6. ↑ Wenthold, P.G.; Kim, J.B.; Jonas, K.-L.; Lineberger, W.C. (1997). An Experimental and Computational Study of the Electron Affinity of Boron Oxide. J. Phys. Chem. A 101 (24): 4472. DOI: 10.1021/jp970645u.
  7. ↑ Travers, M.J.; Cowles, D.C.; Ellison, G.B. (1989). Reinvestigation of the electron affinities of O2 and NO. Chem. Phys. Lett. 164 (5): 449. DOI: 10.1016/0009-2614(89)85237-6.
  8. ↑ Schiedt, J.; Weinkauf, R. (1995). Spin-orbit coupling in the anion. Z. Naturforsch. A 50 (11): 1041. DOI: 10.1515/zna-1995-1110.
  9. ↑ Chaibi, W.; Delsart, C.; Drag, C.; Blondel, C. (2006). High precision measurement of the 32SH electron affinity by laser detachment microscopy. J. Mol. Spectrosc. 239 (1): 11. DOI: 10.1016/j.jms.2006.05.012.
  10. ↑ 10,0 10,1 10,2 10,3 Janousek, Bruce K.; Brauman, John I. (1979). Gas Phase Ion Chemistry 2: 53 (Academic Press).
  11. ↑ Miller, T.M.; Leopold, D.G.; Murray, K.K.; Lineberger, W.C. (1986). Electron affinities of the alkali halides and the structure of their negative ions. J. Chem. Phys. 85 (5): 2368. DOI: 10.1063/1.451091.
  12. ↑ Kim, J.B.; Weichman, M.L.; Neumark, D.M. (2015). Low-lying states of FeO and FeO− by slow photoelectron spectroscopy. Mol. Phys. 113 (15–16): 2105. DOI: 10.1080/00268976.2015.1005706.
  13. ↑ Sheps, L.; Miller, E.M.; Lineberger, W.C. (2009). Photoelectron spectroscopy of small IBr−(CO2)n(n=0–3) cluster anions. J. Chem. Phys. 131 (6): 064304. PMID: 19691385. DOI: 10.1063/1.3200941.
  14. ↑ Zanni, M.T.; Taylor, T.R.; Greenblatt, B.J.; Soep, B.; Neumark, D.M. (1997). Characterization of the anion ground state using conventional and femtosecond photoelectron spectroscopy. J. Chem. Phys. 107 (19): 7613. DOI: 10.1063/1.475110.
  15. ↑ Ervin, K.M.; Ho, J.; Lineberger, W.C. (1988). Ultraviolet photoelectron spectrum of nitrite anion. J. Phys. Chem. 92 (19): 5405. DOI: 10.1021/j100330a017.
  16. ↑ Novick, S.E.; Engelking, P.C.; Jones, P.L.; Futrell, J.H.; Lineberger, W.C. (1979). Laser photoelectron, photodetachment, and photodestruction spectra of O3. J. Chem. Phys. 70 (6): 2652. DOI: 10.1063/1.437842.
  17. ↑ Nimlos, Mark R.; Ellison, G. Barney (1986). Photoelectron spectroscopy of sulfur-containing anions , and ). J. Phys. Chem. 90 (12): 2574. DOI: 10.1021/j100403a007.
  18. ↑ Mead, R.D.; Lykke, K.R.; Lineberger, W.C.; Marks, J.; Brauman, J.I. (1984). Spectroscopy and dynamics of the dipole-bound state of acetaldehyde enolate. J. Chem. Phys. 81 (11): 4883. DOI: 10.1063/1.447515., gevonden via: Rienstra-Kiracofe, J.C.; Tschumper, G.S.; Schaefer, H.F.; Nandi, S.; Ellison, G.B. (2002). Atomic and molecular electron affinities: Photoelectron experiments and theoretical computations 102 (1): 231–282. PMID: 11782134. DOI: 10.1021/cr990044u.
  19. ↑ Adams, C.L.; Schneider, H.; Ervin, K.M.; Weber, J.M. (2009). Low-energy photoelectron imaging spectroscopy of nitromethane anions: Electron affinity, vibrational features, anisotropies, and the dipole-bound state. J. Chem. Phys. 130 (7): 074307. PMID: 19239294. DOI: 10.1063/1.3076892.
  20. ↑ Page, F. M.; Goode, G. C. (1969). Negative ions and the magnetron (John Wiley & Sons). NB.: According to NIST as concerns Boron trifluoride, the Magnetron method, lacking mass analysis, is not considered reliable.
  21. ↑ Ruoff, R.S.; Kadish, K.M.; Boulas, P.; Chen, E.C.M. (1995). Relationship between the Electron Affinities and Half-Wave Reduction Potentials of Fullerenes, Aromatic Hydrocarbons, and Metal Complexes. J. Phys. Chem. 99 (21): 8843. DOI: 10.1021/j100021a060.
  22. ↑ Schiedt, J.; Weinkauf, R. (1999). Resonant photodetachment via shape and Feshbach resonances: p-benzoquinone anions as a model system. J. Chem. Phys. 110 (1): 304. DOI: 10.1063/1.478066.
  23. ↑ Chowdhury, S.; Kebarle, P. (1986). Electron affinities of di- and tetracyanoethylene and cyanobenzenes based on measurements of gas-phase electron-transfer equilibria. J. Am. Chem. Soc. 108 (18): 5453. DOI: 10.1021/ja00278a014.
  24. ↑ Troe, J.; Miller, T.M.; Viggiano, A.A. (2012). Communication:Revised electron affinity of SF6 from kinetic data. J. Chem. Phys. 136 (2): 121102. PMID: 22462826. DOI: 10.1063/1.3698170.
  25. ↑ Mathur, B.P.; Rothe, E.W.; Tang, S.Y.; Reck, G.P. (1976). Negative ions from phosphorus halides due to cesium charge exchange. J. Chem. Phys. 65 (2): 565. DOI: 10.1063/1.433109.
  26. ↑ George, P.M.; Beauchamp, J.L. (1979). The electron and fluoride affinities of tungsten hexafluoride by ion cyclotron resonance spectroscopy. Chem. Phys. 36 (3): 345. DOI: 10.1016/0301-0104(79)85018-1.
  27. ↑ NIST chemistry webbook, gevonden via: Borshchevskii, A.Ya.; Boltalina, O.V.; Sorokin, I.D.; Sidorov, L.N. (1988). Thermochemical quantities for gas-phase iron, uranium, and molybdenum fluorides, and their negative ions. J. Chem. Thermodyn. 20 (5): 523. DOI: 10.1016/0021-9614(88)90080-8.
  28. ↑ Huang, Dao-Ling; Dau, Phuong Diem; Liu, Hong-Tao; Wang, Lai-Sheng (2014). High-resolution photoelectron imaging of cold anions and accurate determination of the electron affinity of C60. J. Chem. Phys. 140 (22): 224315. PMID: 24929396. DOI: 10.1063/1.4881421.
Informatie afkomstig van Wikibooks NL,
een onderdeel van de Wikimedia Foundation.